Coupled valence bond theory

A chemist's guide to valence bond theory

Essay Valence Bond Theory for Chemical Dynamics

This essay provides a perspective on several issues in valence bond theory: the physical significance of semilocal bonding orbitals, the capability of valence bond concepts to explain systems with multireferences character, the use of valence bond theory to provide analytical representations of potential energy surfaces for chemical dynamics by the method of semiempirical valence bond potential...

Valence-bond theory of compounds of transition metals.

An equation relating the strength (bondforming power) of an spd hybrid bond orbital to the angles it makes with other bond orbitals is formulated and applied in the discussion of the structures of transition-metal carbonyls and other substances by the valence-bond method. The rather simple theory gives results that agree well with those obtained by the complicated and laborious calculation of s...

Theory of Valence-bond Lattice on Spin Lattices*

Quantum spin-lattice systems in low dimensions exhibit a variety of interesting zero-temperature phases, some of which show non-classical (i.e., non-magnetic) long-range orders, such as dimer or trimer valence-bond order. These symmetry-breaking systems with localized valence bonds are referred to as valence-bond lattices (VBL) in this article. A review of our systematic microscopic formalism b...

Valence-bond theory of highly disordered quantum antiferro- magnets

We present a large-N variational approach to describe the magnetism of insulating doped semiconductors based on a disorder-generalization of the resonating-valence-bond theory for quantum antiferromagnets. This method captures all the qualitative and even quantitative predictions of the strong-disorder renormalization group approach over the entire experimentally relevant temperature range. Fin...